Metal Complexes and Metals in Macromolecules

Metal Complexes and Metals in Macromolecules

This compact manual is aimed at all organic, inorganic, polymer and physical chemists as well as materials scientists looking for competent and detailed information on the current state of this interdisciplinary area of research.

Author: Dieter Wöhrle

Publisher: Wiley-VCH

ISBN: UOM:39015057010673

Category: Science

Page: 667

View: 248

Metals and metal complexes can form compounds with organic macromolecules that show amazing properties. As is so often the case, nature leads by example. Synthetically produced model compounds, such as phthalocyanines, porphyrines or metalloproteins, as well as metallorganic polymers have aroused much interest in materials science. Their special magnetic, electrochemical and photochemical properties open up new perspectives in microelectronics and sensors. This compact manual is aimed at all organic, inorganic, polymer and physical chemists as well as materials scientists looking for competent and detailed information on the current state of this interdisciplinary area of research. It covers all questions relating to the targeted design of metallic macromolecules, from proven synthesis methods right up to the latest strategies. It also treats major progress in the determination of their structures, the physical-chemical properties of promising compounds and their potential in microelectronics and sensors. Furthermore, the most important methods of synthesis and investigation are presented in detail in an experimental section, while a comprehensive collection of pertinent original literature round s off this unique reference on all matters relating to macromolecular metal complexes.
Categories: Science

Macromolecule Metal Complexes

Macromolecule Metal Complexes

Furthermore, the authors treat the actual working areas for new application methods. In all, a very helpful tool for polymer and materials scientists, as well as organic and physical chemists working in these fields.

Author: Francesco Ciardelli

Publisher: Springer Science & Business Media

ISBN: 9783642609862

Category: Technology & Engineering

Page: 318

View: 886

The first concise overview on the topic, spanning the spectrum from fundamentals to new application areas. The synthesis, kinetics and thermodynamics of these complexes are covered in detail, while much emphasis is placed on special properties such as gas transport, charge transport, catalysis and light-induced processes. Furthermore, the authors treat the actual working areas for new application methods. In all, a very helpful tool for polymer and materials scientists, as well as organic and physical chemists working in these fields.
Categories: Technology & Engineering

Macromolecules Containing Metal and Metal Like Elements Volume 5

Macromolecules Containing Metal and Metal Like Elements  Volume 5

This series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. The fifth volume in this series provides useful descriptions of the transition metals and their applications.

Author: Alaa S. Abd-El-Aziz

Publisher: John Wiley & Sons

ISBN: 9780471727644

Category: Technology & Engineering

Page: 400

View: 308

This series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. The fifth volume in this series provides useful descriptions of the transition metals and their applications. Transition Metals are covered in 2 volumes, the second part is covered in Volume 6.
Categories: Technology & Engineering

Synthesis and Polymerization of Metal Containing Monomers

Synthesis and Polymerization of Metal Containing Monomers

This book overviews methods for the synthesis of metal-containing monomers with various types of metal bonds to the organic moiety of the molecule, such as ionic, covalent, donor-acceptor, and others.

Author: Anatoly D. Pomogailo

Publisher: CRC Press

ISBN: 0849328632

Category: Technology & Engineering

Page: 176

View: 167

This book overviews methods for the synthesis of metal-containing monomers with various types of metal bonds to the organic moiety of the molecule, such as ionic, covalent, donor-acceptor, and others. Published data on homopolymerization, copolymerization, and graft polymerization of these monomers are generalized. Synthesis and Polymerization of Metal-Containing Monomers discusses features typical of the molecular and structural organization of the resulting metal-containing polymers, their properties and the associated major applications, such as catalytical and biological activity, electrophysical characteristics, and thermal resistance.
Categories: Technology & Engineering

Macromolecule Metal Complexes MMC 9

Macromolecule Metal Complexes  MMC 9

A variety of structural design is possible based on the coordination number and
geometry to construct an efficient multiredox system . - - - - - - - - - - - - -
Introduction A combination of transition metals and a - conjugated molecules or
polymers as ...

Author: Kalle Levon

Publisher: John Wiley & Sons

ISBN: 3527304762

Category: Science

Page: 195

View: 915

The 9th IUPAC International Symposium on Macromolecule–Metal Complexes (MMC–9) was held at the Polytechnic University in Brooklyn, NY ; August 19–23,2001. The topics addressed included: – macromolecule–metal complexes in "green Chemistry" – polyelectrolytes and polymer batteries – electronic, magnetic and optical properties of macromolecule–metal complexes – biorelated complexes – physical properties The role of metal ions, complexes and clusters inmacromolecular systems was discussed wherein the polymer systems were either natural or synthetic (organic or inorganic). Plenary and selected lectures are presented in this volume of Macromolecular Symposia. This text is intended for scientists, engineers and other technical personnel who seek a current assessment of the rapidly growing field of macromolecule–metal complexes.
Categories: Science

Macromolecules Incorporating Transition Metals

Macromolecules Incorporating Transition Metals

Metal. Complexes. as. Attractive. Motifs. to. Design. Macromolecules. 2.1.
Introduction. Transition metal complexes, which include organometallic and
coordination compounds, constitute a major class of compounds in chemistry and
occupy a ...

Author: Alaa. S. Abd-El-Aziz

Publisher: Royal Society of Chemistry

ISBN: 9781788010368

Category: Science

Page: 232

View: 129

New materials are required to solve global challenges such as the growing energy demand and reducing the threat of new and re-emerging diseases and infections. Metallopolymers is an exciting and promising area of research and this book focuses on the strategy of incorporating transition metals into macromolecules to design functional materials for addressing such problems. The book starts with an introduction to current global challenges and the role of materials science in tackling these, it then discusses the fundamentals of metallopolymers and their synthesis. The final chapters look at specific applications of the materials from photovoltaics and light-emitting diodes for energy conservation, to biological sensors and drug delivery platforms. Written by leading experts in the field, this book is an ideal reference for students and researchers working in polymer chemistry, organometallic chemistry and materials science interested in both the polymers and its applications in energy and health.
Categories: Science

Macromolecules Containing Metal and Metal Like Elements Volume 7

Macromolecules Containing Metal and Metal Like Elements  Volume 7

BASIC CONSIDERATIONS OF THE COMBINATIONS OF MACROMOLECULES
AND METALS Metal-containing macromolecules or macromolecular metal
complexes consist on the combination of - Organic or inorganic macromolecules.

Author: Alaa S. Abd-El-Aziz

Publisher: John Wiley & Sons

ISBN: 9780471773252

Category: Technology & Engineering

Page: 368

View: 496

This series provides a useful, applications-oriented forum for thenext generation of macromolecules and materials. This volume,seventh in the series, covers nanoscale interactions ofmetal-containing polymers. Example chapters include: * Nanoscale Clusters and Molecular Orbital Interactions inMacromolecular-Metal Complexes * Metal Oxide Clusters as Building Blocks for Inorganic-OrganicHybrid Polymers
Categories: Technology & Engineering

Metal and Metalloid Containing Macromolecules

Metal  and Metalloid Containing Macromolecules

This volume features 30 articles based on presentations given in the Metal- and Metalloid-Containing Macromulecules Symposium at the 39th IUPAC Congress and 86th Conference of the Canadian Society for Chemistry in Ottawa from August 10-15, ...

Author: Alaa S. Abd-El-Aziz

Publisher: John Wiley & Sons

ISBN: 3527307001

Category: Science

Page: 364

View: 966

The past two decades have seen tremendous developments in the field of metal- and metalloid-containing macromolecules. The design of new monomers containing metal and metalloid elements and their subsequent polymerization has resulted in a vast array of inorganic and organometallic polymers with interesting properties and applications. This volume features 30 articles based on presentations given in the Metal- and Metalloid-Containing Macromulecules Symposium at the 39th IUPAC Congress and 86th Conference of the Canadian Society for Chemistry in Ottawa from August 10-15, 2003. The articles, written by some of the leading researchers in the field, describe the synthesis, properties and applications of inorganic and organometallic polymers and the current focuses of research in these fields. The purpose of this symposium was to generate dialogue between these researchers and to allow them to present some of their most recent findings.
Categories: Science

Macromolecules Containing Metal and Metal Like Elements Volume 10

Macromolecules Containing Metal and Metal Like Elements  Volume 10

Metals imbedded within macromolecular protein matrices form the basis for the
photosynthesis of plants. Metal–polymer complexes form the basis for many
revolutionary advances occurring now. The contributors to many of these
advances ...

Author: Alaa S. Abd-El-Aziz

Publisher: John Wiley & Sons

ISBN: 0470604085

Category: Technology & Engineering

Page: 448

View: 730

Metal- and metalloid-containing macromolecules are defined as large molecules (i.e., polymers, DNA, proteins) that contain a metal or metalloid group affiliated with the molecule. This volume describes what is possible with metal-containing polymers where the metal is an essential ingredient in obtaining desired optical and electronic properties. Covering applications in nonlinear optical materials, solar cells, light-emitting diodes, photovoltaic cells, field-effect transistors, chemosensing devices, and biosensing devices, this indispensible guide focuses on the photochemistry and photophysics of metal-containing polymers, with chapters by leading contributors to the core advances in this field.
Categories: Technology & Engineering

Macromolecules Containing Metal and Metal Like Elements Volume 9

Macromolecules Containing Metal and Metal Like Elements  Volume 9

Volume 9 in a scientific research series, covering macromolecules This book, Macromolecules Containing Metal and Metal-like Elements, presents research developments in the study of: supramolecular chemistry, supramolecular architecture and ...

Author: Alaa S. Abd-El-Aziz

Publisher: John Wiley & Sons

ISBN: 0470527048

Category: Technology & Engineering

Page: 368

View: 381

This book series Macromolecules Containing Metal and Metal-like Elements brings new concepts and developments in the titled area of research. Volume 9 focuses attention on the area of supramolecular chemistry, supramolecular architecture and supramolecular self-assemblies that involve materials containing metals and metal-like elements and the potential applications of these interesting hybrid materials.
Categories: Technology & Engineering

Physiologic and Chemical Basis for Metal Toxicity

Physiologic and Chemical Basis for Metal Toxicity

and p-orbitals of the valency shell; these metals exhibit extensive complex
formation in biologic media. The electron-donating oxygen, sulfur, or nitrogen
atoms of the ligands of the macromolecules are the coordinating atoms. If the
metal ...

Author: B. Venugopal

Publisher: Springer Science & Business Media

ISBN: 9781468429527

Category: Medical

Page: 238

View: 411

Our purpose is to provide understanding for appropriate use of metals in a technical society. Knowledge of metal toxicity is needed for the preven tion, prediction, diagnosis, and therapy of adverse reactions from excess metals in mammals. Metal Toxicity in Mammals is presented in two volumes. Volume 1, Physiologic and Chemical Basis for Metal Toxic ity, provides the basis for understanding the toxic actions of metals recorded in Volume 2, Chemical Toxicity of Metals and Metalloids. The details and bases for many concepts summarized in Volume I are given, with appropriate references, in Volume 2. Thus, references for specific items in Volume 2 are not generally given in Volume 1. The authors reviewed the known toxicity of several heavy metals in anticipation of their use as multinutrient markers for NASA. As more and more metals were considered, the need for a complete review became obvious. This treatise supplants onerous searches of metal-toxicity litera ture up to 1975 and reviews the toxicity of all the metals of the periodic table on the basis of available relevant data. Books on pharmacological, nutritional, medical, veterinary, or industrial toxicity contain information about selected metals. More complete data about metals of public concern, such as mercury, lead, and cadmium, may be found in numerous books and reviews. The reader should refer to general texts and basic reference works, when specific references are not given, for general information.
Categories: Medical

Total Reflection X Ray Fluorescence Analysis and Related Methods

Total Reflection X Ray Fluorescence Analysis and Related Methods

They are highly relevant to the biosphere because of their ability to form various
metal complexes (about 1 mmol heavy metals per g of HS). Metals and their
macromolecular species have been determined in aquatic HS by TXRF [39].

Author: Reinhold Klockenkämper

Publisher: John Wiley & Sons

ISBN: 9781118988961

Category: Science

Page: 552

View: 582

Explores the uses of TXRF in micro- and trace analysis, and insurface- and near-surface-layer analysis • Pinpoints new applications of TRXF in different fieldsof biology, biomonitoring, material and life sciences, medicine,toxicology, forensics, art history, and archaeometry • Updated and detailed sections on sample preparationtaking into account nano- and picoliter techniques • Offers helpful tips on performing analyses, includingsample preparations, and spectra recording and interpretation • Includes some 700 references for further study
Categories: Science

Macromolecules Containing Metal and Metal Like Elements Volume 1

Macromolecules Containing Metal and Metal Like Elements  Volume 1

The first volume in this series consists of a number of reviews of the field, to give the reader a background to build upon.

Author: Alaa S. Abd-El-Aziz

Publisher: John Wiley & Sons

ISBN: 9780471466581

Category: Technology & Engineering

Page: 280

View: 535

Metal- and metalloid-containing macromolecules are defined as largemolecules (i.e., polymers, DNA, proteins) that contain a metal ormetalloid group affiliated with the molecule. The first volume inthis series consists of a number of reviews of the field, to givethe reader a background to build upon. Compiled by an all-star castof macromolecular experts, this guide: Provides useful descriptions of applications for the reader toapply in his/her research into materials, polymers, andmedicine/drug development. Covers non-linear optical materials, speciality magneticmaterials, liquid crystals, anticancer and antiviral drugs,treatment of arthritis, antibacterial drugs, antifouling materials,treatment of certain vitamin deficiencies, electrical conductorsand semiconductors, piezoelectronic materials, electrodes, UVabsorption applications, super-strength materials, speciallubricants and gaskets, selective catalytic and multisite catalyticagents.
Categories: Technology & Engineering

Ecology of Humic Substances in Freshwaters

Ecology of Humic Substances in Freshwaters

The assessed metals (Al, Cu, Fe, Mn, Pb, and Zn) are predominantly enriched in
the macromolecular and ... It is highly probable that the relatively rapid Cu(II)
exchange occurs preferentially with macromolecular metal complexes, whereas
the ...

Author: Christian Steinberg

Publisher: Springer Science & Business Media

ISBN: 3540439226

Category: Science

Page: 440

View: 440

Humic Substances color all waters more or less brown. Their concentrations exceed all carbon of living organisms by at least one order of magnitude. Opposite to former paradigms, they participate in almost any metabolic pathway. They protect against UV-irradation, enable indirect photolysis and, thus, purify hazardous chemicals, they provide inorganic and organic nutrients, may form cryptic genes with DNA and dampen metabolic fluctuations. More recently they can increase adverse effects of hazardous chemicals and they can directly interfere with organisms. The book tries to relate effects to structural features.
Categories: Science

The Porphyrin Handbook

The Porphyrin Handbook

Announcing the sequel to the first ten volumes of The Porphyrin Handbook, which provided an authoritative treatise on the porphryin system and dealt in fine detail with the synthesis, chemistry, spectroscopy, and applications of porphyrins.

Author: Karl M. Kadish

Publisher: Elsevier

ISBN: 0123932203

Category: Science

Page: 3000

View: 962

Announcing the sequel to the first ten volumes of The Porphyrin Handbook, which provided an authoritative treatise on the porphryin system and dealt in fine detail with the synthesis, chemistry, spectroscopy, and applications of porphyrins. The ten latest volumes 11-20 address those major disciplinary areas not covered in the first, including biology and medical implications of porphyrin systems, the biosynthesis of porphyrins, chlorophylls and vitamin B12. Other areas include the multitude of genetically transmitted and drug induced diseases associated with errors in heme metabolism, the transformations of hemes into bile pigments, the organic syntheses of bilins, very recent work on phytochrome, and the pathways of degradation of chlorophyll in senescent plants. In addition, volumes 11-20 address every aspect of synthesis, chemistry, structure and spectroscopy of phthalocyanines which will appeal to scientists in fields ranging from mathematics through physics, chemistry and biochemistry, to biology and medicine. . By the same Editors as the successful first Porphyrin Handbook, published in 2000. . Consists of 61 chapters written by internationally recognized experts. . Clear, concise, and uniform presentation with many hundreds of figures, tables and structural formulae. Including volume indices and cumulative index.
Categories: Science

Houben Weyl Methods of Organic Chemistry Vol E 23o 4th Edition Supplement

Houben Weyl Methods of Organic Chemistry Vol  E 23o  4th Edition Supplement

279 c) Organosilyl compounds containing metals from Groups VI ± VIII of the
Periodic Table . ... 282 b) And complexes of transition metals that contain
halogen or hydrogen on the metal . ... 324 Macromolecular organosilicon
compounds .

Author: Houben-Weyl,

Publisher: Georg Thieme Verlag

ISBN: 9783131827647

Category: Science

Page: 872

View: 854

Houben-Weyl is the acclaimed reference series for preparative methods in organic chemistry, in which all methods are organized accor ding to the class of compound or functional group to be synthesized. The Houben-Weyl volumes contain 146 000 product-specific experi mental procedures, 580 000 structures, and 700 000 references. The preparative significance of the methods for all classes of compou nds is critically evaluated. The series includes data from as far back as the early 1800s to 2003. // The content of this e-book was originally published in 2000.
Categories: Science

The Porphyrin Handbook

The Porphyrin Handbook

Scientists in such fields as mathematics, physics, chemistry, biochemistry, biology, and medicine are currently involved in investigations of porphyrins and their numerous analogues and derivatives.

Author: Karl Kadish

Publisher: Elsevier

ISBN: 0123932033

Category: Science

Page: 425

View: 889

Scientists in such fields as mathematics, physics, chemistry, biochemistry, biology, and medicine are currently involved in investigations of porphyrins and their numerous analogues and derivatives. Porphyrins are being used as platforms for the study of theoretical principles, as catalysts, as drugs, as electronic devices, and as spectroscopic probes in biology and medicine. The need for an up-to-date and authoritative treatise on the porphyrin system has met with universal acclaim amongst scientists and investigators.
Categories: Science

Photocatalysis

Photocatalysis

Author: Masao Kaneko

Publisher: Springer

ISBN: 3540434739

Category: Science

Page: 360

View: 610

This book gives a comprehensive treatment of photocatalysis, a topic of increasing importance due to its essential role in many of todays environmental and energy-source problems. The first part presents a brief introduction to the principles and fundamental aspects of photocatalysis including photoelectric chemical semiconductors. Part II describes applications to environmental cleaning, such as water purification and cleaning of the atmosphere. Part III discusses applications to photoenergy conversion, for example water decomposition with TiO2, semiconductors and metal complexes. Serving as a timely and convenient reference source including exciting new advances, the book will appeal to academic and industrial researchers as well graduate and advanced undergraduate students.
Categories: Science

Macromolecules Containing Metal and Metal Like Elements Volume 3

Macromolecules Containing Metal and Metal Like Elements  Volume 3

The appearance of metal-containing macromolecules in the human body is
extensive and includes such metals as iron ... Thus, the Zn(II) complex of
xylylbicyclam is a potent anti-HIV agent because it recognizes and binds to the
coreceptor ...

Author: Alaa S. Abd-El-Aziz

Publisher: John Wiley & Sons

ISBN: 9780471683759

Category: Technology & Engineering

Page: 212

View: 548

Metal and metalloid-containing compounds exhibit a wide range ofbiological and biocidal activities, some of which have beenemployed in medicines and drugs. Polymers containing metal ormetalloid functions become a natural extension of this effort; justas organic compound drugs have been chemically bound to polymers orphysically imbibed into polymer matrices in order to provide avariety of useful advantages, the same opportunities exist forusing metal and metalloid species. This volume will cover importantbiomedical applications of organometallic compounds, includingmetal-labeled DNA on surfaces, artificial metallo-DNA, organotinmolecules as anti-cancer drugs, and much more. * Provides useful descriptions of biomedical applications for thereader to apply in his/her research into materials, polymers, andmedicine/drug development. * Edited by high-quality team of macromolecular experts from aroundthe world
Categories: Technology & Engineering

Macromolecular Science and Engineering

Macromolecular Science and Engineering

This book is the first attempt to provide a background perspective to the research field of polymeric and organic materials and it will be of great value to both professional researchers and postgraduate students.

Author: Yoshikazu Tanabe

Publisher: Springer Science & Business Media

ISBN: 9783642585593

Category: Technology & Engineering

Page: 401

View: 820

Covering current advances in the science and technology of polymeric and organic materials, each chapter is a self-contained review of progress, and particular emphasis has been placed on obtaining an overall understanding of the state of the art in each area. This is the first book to provide a background perspective on this field of research, and is suitable for both professional researchers and postgraduate students.
Categories: Technology & Engineering